Зміст книги 

Preface

Chapter 1. Chemical thermodynamics

Thermodynamic system

Thermodynamic parameters and thermodynamic processes

Internal energy

Enthalpy

Standard enthalpy change

The Hess’ law

Calorimetry

Energy values of nutrients

The First Law of Thermodynamics 

Entropy

Second Law of Thermodynamics 

Free energy

Spontaneous processes

Macroergic compounds in the organism

Chapter 2. Chemical kinetics

Rate of chemical reaction

Factors that affect reaction rate

Effect of concentrations of substances on reaction rate.
Law of mass action

Molecularity of reactions

Reaction order

Effect of temperature on reaction rate

Recap of collision theory of reaction rate

Complex reactions

Catalysis

Properties of catalysts

Important concepts of catalysis

Catalysis by phase: heterogeneous and homogeneous catalysts

Catalysis by chemical interaction: acid-base and redox catalysts

Mechanism of catalysis

Theories of catalysis

Enzymes

Properties of enzymes

Measuring enzyme activity

Classification of enzymes

Properties of the active site

Kinetics and mechanism of enzyme activity

Factors affecting velocity of enzymic reactions

Inhibition of enzyme activity

Regulation of enzyme activity

Medical enzymology

Chapter 3. Chemical equilibrium. Heterogeneous equilibriums in the organism

Chemical equilibrium

Kinetics of chemical equilibrium

Factors affecting chemical equilibrium. Le Chatelier’s principle

Thermodynamics of chemical equilibrium

Solubility product. Heterogeneous equilibriums in the organism

Solubility product

Heterogeneous equilibriums in the organism

Formation and remodeling of bone tissue

Formation of kidney stones

Chapter 4. Biogenic elements

Classification of biogenic elements by the amount in the organism

Classification of biogenic elements by the electron structure of the valence shell

Macroelements

Macroelements of the s-block

Macroelements of the p-block

Microelements

Microelements of the s-block

Microelements of the p-block

Microelements of the d-block

Сhapter 5. Coordination complexes

Structure of coordination complexes

Coordination number and denticity of ligands

Donor-acceptor mechanism of bond formation

Isomerism of coordination complexes

Classification of coordination complexes

Nomenclature of coordination complexes

Stability constant of coordination complexes

Chelate complexes

Coordination complexes in the organism

Chapter 6. Solutions. Solubility. Composition of solutions

Solutions

Classification of solutions

Solubility

Polarity

Mechanism of dissolution

Solubility of gases in liquids

Transport of gases in blood

Nernst distribution law

Composition of solutions

Mass fraction

Mole fraction

Molarity

Normality

Molality

Measurements of concentration of solutions. Titrimetric analysis

Methods of titrimetric analysis by chemical reaction

Acid-base titration

Complexonometric titration

Redox titration

Precipitation titration

Methods of titrimetric analysis by technique

Colligative properties of solutions

Vapor pressure depression

Equilibrium vapor pressure

Raoult’s Law

Boiling point elevation

Freezing point depression

Osmosis

Osmotic pressure

Osmolarity and osmolality

Isotonic, hypotonic, and hypertonic solutions

Plasmolysis and hemolysis

Solutions isotonic to blood

The osmotic pressure of blood. Osmoregulation

Chapter 7. Acids and bases. Buffer solutions

Electrolytes

Acids and bases

Ion theory (Arrhenius definition)

Proton theory (Brønsted-Lowry definition)

Electron theory (Lewis)

Dissociation of water

pH

Salt hydrolysis

Hydrolysis constant

Degree of salt hydrolysis

Buffer solutions

Types of buffer solutions

Mechanism of buffering

Buffer capacity

pH of buffer solutions. Henderson—Hasselbalch equation

Acid-base homeostasis

Buffer systems of blood

Disorders of acid-base homeostasis

Chapter 8. Electrode processes

Electrode potential

Galvanic cell. Electromotive force

Potentiometry

Diffusion potential

Membrane potential

Redox systems. Redox potentials

Redox reactions in the organism. Biological oxidation

Chapter 9. Surface phenomena. Adsorption. Chromatography

Surface phenomena

Adsorption

Surface phenomena at liquid-gas phase interfaces.
Surface tension

Surface-active compounds

Surface phenomena at liquid-liquid phase interface.
Emulsions

Surface phenomena at immobile phase interfaces

Molecular adsorption

Chromatography

Methods of chromatography by aggregate state of phases

Methods of chromatography by type of interaction

Methods of chromatography by technique

Chapter 10. Disperse systems. Colloidal solutions

Disperse systems

Colloidal solutions

Purification of colloidal solutions

Preparation of colloidal solutions

Structure of colloidal particles

Molecular-kinetic properties of colloidal solutions

Electrokinetic properties of colloidal solutions

Optical properties of colloidal solutions

Stability of colloidal solutions

Coagulation of lyophobic colloidal solutions

Flocculation

Colloidal protection

Chapter 11. High-molecular compounds and their solutions

Classification of polymers

Synthesis of polymers

Biopolymers

Proteins

Polysaccharides

Nucleic acids

Isoelectric point (pI) of proteins

Properties of polymer solutions

Viscosity of polymer solutions

Dissolution of polymers. Swelling

Gels

Index words